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HDL in metabolic syndrome have been reported to have decreased capacity to prevent oxidation of LDL and inhibit endothelial cell apoptosis (877,878)

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Although this enzyme can also inactivate (11-dehydrogenase activity) cortisol and corticosterone by catalyzing the oxidation reactions converting cortisol to cortisone and corticosterone to 11-dehydrocorticosterone, these inactivating reactions are of minimal significance to intracellular glucocorticoid regulation

doi: 10.1016/s0003-9861(03)00166-8

In addition to glycolysis, subsequent pathways involved in glucose metabolism, and therefore in eventual ATP formation, demonstrate the structural and functional alteration of protein components due to increased oxidation