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Unexpected second-sphere hydrogen peroxide binding site We previously demonstrated that residues Gln143, Tyr166, His30, and Tyr34 have unusual pK a s and undergo changes in protonation states during the MnSOD PCET cycle (Fig

Mitchell KG, Parra ER, Nelson DB, Vaporciyan AA, Hofstetter WL, Mehran RJ, Swisher SG, Rice DC, Sepesi B, Walsh GL, Zhang J, Behrens C, Kalhor N, Weissferdt A, Moran CA, Wistuba II, Fujimoto J, Roth JA, Antonoff MB

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