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The reason for occurring this phenomenon (reduction of CySGly- but not of GS-bound Mercury(II)) in solution and in the biological environment of cells is reasonably a consequence of the low reducing electrochemical potential of CySGly (at 0.282 V the most reducing one of the whole soluble physiological thiolome)

Abbreviations APAP: acetaminophen, gamma-GT: gamma-glutamyltranspeptidase, GCLC: glutamyl-cysteine ligasecatalytic subunit GPx: GSH peroxidases, GSH: glutathione, GSSG: oxidized GSH, GST: glutathione S-transferase, HIC: hemin-induced cytotoxicity, Keap1: Kelch-like ECH associated protein 1, MRP: multidrug-associated resistance protein, MS: mass spectrometry NAC: N-acetyl cysteine, NAPQI: N-acetyl p-benzoquinone imine, Nrf2: nuclear factor erythroid 2-related factor-2, PGAs: prostaglandins, RBCs: red blood cells, RNS: reactive nitrogen species, ROS: reactive oxygen species, TF: transcription factor

PLoS One 8 (10), e76146

Other complications may arise further down the line, however, as a result of damage to the nerve, warranting a visit to a GP

10.1126/science.aac4255 Science