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A study reported that MDA and 4-HNE levels were higher in the frontal brain of ASD patients (186)

doi: 10.1038/nm.2208

These hormones regulate melanogenesis not only through genomic and non-genomic signaling pathways that directly modulate melanogenic enzymes (e.g., TYR, TRP-1, TRP-2) and transcription factors (e.g., MITF) but also by interacting with oxidative stress, inflammatory responses, and vascular remodeling, thereby establishing a complex molecular network that exacerbates hyperpigmentation

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279: H672-H678

Proc Natl Acad Sci USA 95:34783482 Maywald M, Wessels I, Rink L (2017) Zinc signals and immunity