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Given these properties, hydrogen has recently emerged as a green extraction method that can serve as an alternative to traditional solvents for phytochemical extraction and the utilization of agricultural food waste (157, 158)

Formation of apoptosome is initiated by cytochrome c-induced dATP hydrolysis and subsequent nucleotide exchange on Apaf-1

31 SchneiderA.Martin-VillalbaA.WeihF.VogelJ.WirthT.SchwaningerM

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327 Nonenzymatic oxidation of 13-HpOTrE into a small amount (7%) of 13-oxo-OTrE at room temperature in dichloromethane and in the presence of 5,10,15,20-tetraphenyl-21 H ,23 H -porphyrin iron(III) chloride (TPP/Fe(III)) and 2,4,6-tri- tert -butylphenol, which generate an alkoxyl anion from the hydroperoxide, has been reported by Wilcox et al., 298 whereas the formation of a small amount (1.2%) of all- trans ketones (10( E ),12( E )-9-oxo-ODE and 9( E ),11( E )-13-oxo-ODE) by photosensitized oxidation of LA-derived 9- and 13-HpODEs has been described by Neff in the presence of methylene blue at 0 C in dichloromethane (Scheme 37)