glutathione s transferase polymorphisms and their biological consequences Modulation of Glutathione-S-Transferase by Phytochemicals: To Activate or Inhibit—That Is the Question Alterations in the glutathione and

Wu L, Xu S, Cheng X, Zhang L, Wang Y, Wu J, et al

doi: 10.1016/S2215-0366(15)00309-0

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Among them, diacylglycerol activates PKC and impairs IRS-1 activation, while ceramides activate protein kinase C zeta (PKC) and protein phosphatase 2A (PP2A), resulting in dephosphorylation of Akt, 31,32 and promoting gluconeogenesis