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Sharpless asymmetric epoxidation [46], BINOL-Ti-catalyzed allylation [47], and asymmetric hydrogenation using BINAP-Ru catalysts [48] achieve high enantioselectivity

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Importantly, some drugs such as proteins and peptides are inappropriate for oral administration because they are significantly degraded by gastric acid and proteolytic enzymes in the gastrointestinal (GI) tract, and rapidly metabolized by the first-pass effect in the liver

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Neurology 93 , e2294e2305 (2019)

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