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Acknowledgements The authors thank the Brazilian Coordination for the Improvement of Higher Education Personnel (CAPES), the Brazilian National Council for Scientific and Technological Development (CNPq), the Instituto Tecnolgico Vale and Vale for the financial support in the development of this work and for the scholarships provided

Two commonly prescribed antifungals are fluconazole/Diflucan (for all types of Candida ) and nystatin (for oral thrush)

Basically a study looked at 100 drugs & found that 90% of them were fully potent 15 years after their expiration date, though that may vary by drug, and perhaps liquid forms are a bit more vulnerable (perhaps)

111,112 Mn II plays many diverse roles in biology, 113 including that of Lewis acid in transformations that do not require a change in oxidation state, e.g., in phosphatases, arginase and a number of metabolic enzymes, but also in other contexts where Mn III and higher oxidation states are reached, including Mn-superoxide dismutase, some ribonucleotide reductases, and the oxygen evolving complex in plants